Izuagie, Anthony A.Gitari, Wilson M.Gumbo, Jabulani R.2016-08-192016-08-192015-08-27To cite this article: Anthony A. Izuagie, Wilson M. Gitari & Jabulani R. Gumbo (2015): Defluoridation of groundwater using diatomaceous earth: optimization of adsorption conditions, kinetics and leached metals risk assessment, Desalination and Water Treatment, DOI: 10.1080/19443994.2015.1083894To link to this article: http://dx.doi.org/10.1080/19443994.2015.1083894http://hdl.handle.net/11602/634The original article can be accessed at http://dx.doi.org/10.1080/19443994.2015.1083894In Sub-Saharan Africa, many rural communities depend on boreholes as the most appropriate source of water supply. Sadly, water from some of the boreholes contains fluoride above the WHO guideline of 1.5 mg/L. Hence, defluoridation is necessary. The aim of this study is to investigate the fluoride uptake capacity of diatomaceous earth (DE), a natural resource at optimized conditions by batch method. X-ray fluorescence analysis showed that the major component is silica (83.1%), while Al2O3 is the main minor component. XRD shows it is an amorphous material. For 8 mg/L fluoride spiked water, the highest per cent fluoride removal at optimum adsorption conditions (contact time: 30 min, adsorbent dosage: 8 g/L, pH 2, temperature: 298 K and shaking speed: 200 rpm) was between 23.4 and 25.6%. PO3 4 in tested field water was observed to reduce the fluoride uptake capacity of fluoride. The sorption data fitted better into Freundlich isotherm than Langmuir isotherm. Fluoride sorption process was found to be a second-order kinetic. Inductively coupled plasma-mass spectrometer analysis of treated water revealed that metal and non-metal species were released at trace levels. Modification of DE would be necessary to enhance the fluoride adsorption capacityenDefluoridationUCTDOptimizationKineticsLeached metalsAssessmentArticleIzuagie Anthony A, Gitari Wilson M, Gumbo Jabulani R. Defluoridation of groundwater using diatomaceous earth : optimization of adsorption conditions, kinetics and leached metals risk assessment. 2015; http://hdl.handle.net/11602/634.Izuagie, Anthony A., Gitari, Wilson M., & Gumbo, Jabulani R. (2015). Defluoridation of groundwater using diatomaceous earth : optimization of adsorption conditions, kinetics and leached metals risk assessment. http://hdl.handle.net/11602/634Izuagie, Anthony A., Wilson M. Gitari, and Jabulani R. Gumbo "Defluoridation of groundwater using diatomaceous earth : optimization of adsorption conditions, kinetics and leached metals risk assessment." (2015) http://hdl.handle.net/11602/634TY - Article AU - Izuagie, Anthony A. AU - Gitari, Wilson M. AU - Gumbo, Jabulani R. AB - In Sub-Saharan Africa, many rural communities depend on boreholes as the most appropriate source of water supply. Sadly, water from some of the boreholes contains fluoride above the WHO guideline of 1.5 mg/L. Hence, defluoridation is necessary. The aim of this study is to investigate the fluoride uptake capacity of diatomaceous earth (DE), a natural resource at optimized conditions by batch method. X-ray fluorescence analysis showed that the major component is silica (83.1%), while Al2O3 is the main minor component. XRD shows it is an amorphous material. For 8 mg/L fluoride spiked water, the highest per cent fluoride removal at optimum adsorption conditions (contact time: 30 min, adsorbent dosage: 8 g/L, pH 2, temperature: 298 K and shaking speed: 200 rpm) was between 23.4 and 25.6%. PO3 4 in tested field water was observed to reduce the fluoride uptake capacity of fluoride. The sorption data fitted better into Freundlich isotherm than Langmuir isotherm. Fluoride sorption process was found to be a second-order kinetic. Inductively coupled plasma-mass spectrometer analysis of treated water revealed that metal and non-metal species were released at trace levels. Modification of DE would be necessary to enhance the fluoride adsorption capacity DA - 2015-08-27 DB - ResearchSpace DP - Univen KW - Defluoridation KW - Optimization KW - Kinetics KW - Leached metals KW - Assessment LK - https://univendspace.univen.ac.za PY - 2015 T1 - Defluoridation of groundwater using diatomaceous earth : optimization of adsorption conditions, kinetics and leached metals risk assessment TI - Defluoridation of groundwater using diatomaceous earth : optimization of adsorption conditions, kinetics and leached metals risk assessment UR - http://hdl.handle.net/11602/634 ER -